Trigonal Bipyramidal Rhodium(I) Methyl and Phenyl Complexes: Precursors of Oxidative Methyl and Phenyl Radical Generation
نویسندگان
چکیده
The new complexes [Rh(Me)(trop3P)] (2) and [Rh(Ph)(trop3P)] (3) (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) were synthesised by addition of organolithium reagents (MeLi PhLi) to the parent pentacoordinated chloride complex [RhCl(trop3P)]. compounds have a trigonal bipyramidal structure with olefin-only ligands in equatorial position methyl or phenyl substituent axial position. Oxidation 2 3 leads liberation radicals, which indirectly detected reaction common spin trapping reagents.
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ژورنال
عنوان ژورنال: Inorganics (Basel)
سال: 2022
ISSN: ['2304-6740']
DOI: https://doi.org/10.3390/inorganics10030028